Cinnabar and Vermilion: Beautiful and Toxic Mineral and Pigment
An Attractive and Useful Mineral
Cinnabar is a beautiful orange red to dark red mineral that is prized for both its color and its mercury content. In ancient times, it was ground into a powder to form a pigment called vermilion. This pigment was used for art and decoration and was also added to cosmetics. It's still used in artists’ paints today, although it's often replaced by synthetic and less toxic pigments.
The mineral is made of a compound called mercury (ll) sulfide or mercuric sulfide. The chemical formula of this compound is HgS. Mercury (ll) sulfide occurs in two forms in nature—the more common red or cinnabar form and the rarer black or metacinnabar form. Mercury and mercury compounds are toxic to humans, although cinnabar is not as poisonous as some other forms of mercury.
Cinnabar is usually found in rocks that form near volcanic activity or in hot springs. It’s produced near the Earth’s surface from hot liquids that bubble up from deeper in the Earth. Most of the world’s mercury supply is obtained from the mineral. Major cinnabar producers today include Spain, China, Italy, Serbia, Slovenia, and parts of the United States.
Uses of Cinnabar in the Past
Cinnabar, vermilion, mercury (ll) sulfide, and mercuric sulfide all refer to the same substance (with the exception of the rare black form of mercury (ll) or mercuric sulfide). Like several other red materials in nature, cinnabar was also known by the evocative name of “dragon’s blood” in earlier times. Its vibrant red color was a great attraction for people looking for pigments.
Ancient Romans created paintings and decorated statues and their faces with ground cinnabar mixed with a medium such as egg yolk or plant gums. The Mayan people used the mineral to decorate burial chambers, the sarcophagi, and the dead bodies of important members of their society.
Earlier women in India wore vermilion along the parting of their hair and in a dot on their foreheads to indicate that they were married. Some modern Indian women still follow this custom. Today the pigment, which is known as sindoor, is made of turmeric, lime juice, and other substances instead of cinnabar.
Ancient Chinese people used cinnabar in their famous red lacquers and in special inks. The technique for making artificial vermilion from mercury and sulfur was apparently first devised in China in the eighth century. Vermilion from China is sometimes known as China Red.
Art in the Villa of Mysteries
Examples of historical art created with vermilion may include the paintings in the Ancient Roman villa shown in the video below. Though the pigment is often said to have been responsible for the red color in the frescoes found in the villa, some researchers disagree with this idea.
The frescoes may not have been as richly colored in the past as they are today. They've been preserved with a wax layer, which darkened the paint when it was applied. The paintings are gradually being restored to their natural color as well as being protected by new methods.
The name of the villa that has left us such interesting art is the Villa of (the) Mysteries. It stands just outside the city of Pompeii. The building was affected by the famous eruption of Mount Vesuvius in 79 A.D., but not to the same extent as many other buildings in the area.
The Villa of the Mysteries is believed to have been used for initiation into a mystery cult of Dionysus, the god of wine. The murals on the walls appear to depict initiates and their experiences, although expects are not certain about the meaning of all of the paintings. The murals are frescoes, which are paintings created on wet plaster that become an integral part of a wall. According to the Italian Ministry of Cultural Heritage and Activities, some of the scenes in the frescoes show the drinking of wine and ecstatic dancing, which were rituals of the mystery cult.
Color Change in Vermilion
Unfortunately, in some cases vermilion used in historical art has turned brown, black, or grey over time. The color loss from the pigment is of great concern to art historians and to those working in art conservation.
Researchers have discovered a chemical reaction that might be responsible for vermilion's loss of color. They say that chlorine salts in the air may act as a catalyst for a reaction that releases mercury from the pigment when it's exposed to light. The thin layer of tiny mercury particles on top of the vermilion may give the mineral a dark appearance. The grey color over some vermilion might be due to the production of mercury (l) chloride, which is white in color. Some researchers think that the change in the pigment's appearance is a more complex process than this, however.
Once the cause or causes of vermilion's color change have been discovered, it may be possible to protect historical art from further damage. If a way to reverse the damage is discovered, it might even be possible to return the art to its former glory.
Mercury (ll) Sulfide in an Inca Burial Site
In 2018, researchers performed an analysis of a red powder found at an Inca burial site in northern Chile. The site contained the remains of two mummified girls dressed in richly colored red clothing. The remains were discovered in 1976, but studies of the remains have been ongoing. The analysis showed that the red powder consisted of 95% cinnabar, or HgS. This is interesting historically, but it’s also a cautionary tale for archaeologists exploring similar sites. HgS powder can easily enter the body and is dangerous.
The girls are believed to have been buried 500 to 600 years ago and were approximately nine and eighteen years old at the time. They were accompanied by many items and are believed to have died in a ritual sacrifice. The only known source of cinnabar from the time period was a mine located a long distance away. These facts suggest that the girls had high status and that their sacrifice was very significant. The Incas performed the ritual sacrifice of children (capacocha) as a way to honor an emperor or to prevent or alleviate a natural disaster.
Uses of Cinnabar Today
In more recent times, powdered cinnabar or vermilion was added to candies as a food coloring, although it's no longer used for this purpose. The mineral is still part of many traditional Chinese medicines, however.
Cinnabar in the form of natural or artificially made vermilion is sold today as an artist’s paint. The paint is accompanied by a warning to avoid ingestion and skin contact. Many artists use cadmium red as a replacement for vermilion because it's safer and more permanent.
Some rock and mineral collectors like to include cinnabar samples in their collection. The color of the mineral varies considerably and ranges from orange to a deep purple-red. Some people enjoy the hunt for the perfect specimen.
The main use of cinnabar today is for mercury production. To extract mercury from cinnabar, the mineral is heated. The mercury escapes from the mineral as a gas, which is then cooled and condensed to make liquid mercury. Mercury is the only metal that is liquid at room temperature. It needs to be treated with great caution because it can be absorbed through the skin and releases dangerous vapors.
The early alchemists called mercury “quicksilver” for two reasons. One is that mercury is silver in color. The other is that when it’s placed on a surface it forms beads that roll around as though they are alive.
Other Meanings of the Word Cinnabar
The word "cinnabar" is sometimes used to name items unrelated to the mineral in order to convey an exotic impression. For example, Cinnabar perfume contains no mercury. Today's cinnabar boxes are generally made of wood that is covered by a red lacquer containing no cinnabar or by a red resin polymer. The lacquer or resin is imprinted with a design. Cinnabar jewelry doesn't contain the mineral, since mercury compounds shouldn't stay in contact with the skin.
Mercury exists in three forms—elemental mercury (pure metallic mercury), organic mercury (mainly methylmercury, the form found in some fish), and inorganic mercury, such as the mercury (ll) sulfide that makes up cinnabar. Unlike organic mercury, inorganic mercury doesn't contain carbon.
The severity of mercury poisoning in humans depends on many factors, including:
- the form of mercury
- the way in which it's absorbed into the body (through ingestion, inhalation, or skin absorption)
- the dose of mercury absorbed
- the duration of the exposure
- the frequency of the exposure
- the age and health of the affected person
Mercury poisoning can result in damage to the nervous and muscular systems as well as damage to the gastrointestinal tract, kidneys, and respiratory system.
Inorganic Mercury Toxicity
Inorganic mercury such as the mercury found in cinnabar is the least toxic form of mercury, but it's still poisonous.
- Inorganic mercury is absorbed through the lining of the digestive tract, but in lower quantities than organic mercury.
- Inorganic mercury doesn’t vaporize much at room temperature, so inhalation is not a major problem. The dust is dangerous for the lungs, however.
- Small amounts of inorganic mercury compounds can be absorbed through the skin.
- Contact with high levels of inorganic mercury can cause skin rashes.
- Although it’s less likely to cause nervous system damage than other forms of mercury, chronic exposure to inorganic mercury can damage the kidneys and the nervous system.
Toxicity and Safe Use of Cinnabar
There is uncertainty about how poisonous cinnabar is and about the amount required to produce dangerous effects. Scientists generally recommend that we limit our exposure to all mercury compounds, however, including inorganic mercury.
People using cinnabar are warned not to inhale the dust and to be very careful when breaking the mineral in case dust is created. The mineral mustn’t be ingested or licked. In addition, it mustn’t be heated, which might trigger mercury vapor release. Opinions are divided about whether cinnabar is safe to touch. Mercury (ll) sulfide can be absorbed through the skin, but how much is actually absorbed from a lump of cinnabar mineral is unknown. Since there are unanswered questions about the mineral's safety, it's best to wear gloves when handling it.
One potentially serious problem is that sometimes drops of liquid mercury can be found in a piece of cinnabar mineral, which are more dangerous than the mineral itself. Liquid mercury releases a poisonous vapor.
A Beautiful Mineral
Cinnabar is a beautiful mineral. Its uses are interesting and the artistic legacy left by the mineral is wonderful. It's potentially dangerous, however. Anyone coming into close contact with the mineral—especially if this happens on a frequent basis—should be aware of important safety precautions. It's lovely to be able to admire cinnabar at close range, as long as this is done safely.
Cinnabar information from mindat.org (an online mineralogical database)
Facts about vermilion from the Pigments through the Ages section at webexhibits.org
Mercury facts in relation to health from the CDC (Centers for Disease Control and Prevention)
Information about the Villa of the Mysteries in Pompeii from the website of the Italian Ministry of Cultural Heritage and Activities
Darkening of vermilion over time from the APS (American Physics Society)
Cinnabar powder in an Inca burial from ScienceAlert
Questions & Answers
- Helpful 2
Is cinnabar renewable?
Cinnabar is a mineral. The Earth's minerals are classified as nonrenewable resources. Though new samples of minerals do form, the process takes longer than the human lifespan.
© 2011 Linda Crampton